Pokémon Black and White 2 Will using Thunder Stone when just evolved make King Mamma Electric Eel unable to learn unevolved skills?

The evolved ones won't learn the skills before they evolve that's for sure, as for how many levels he has to evolve,

Lv.39 Bite Crunch かみくだく Crunch 80 100% 15 Single Black/White Black2/White2

Lv.44 100,000 Volt 10 Mamavolts Thunderbolt 95 100% 15 Single Black/White Black2/White2

Lv.49 Acid Bomb アシッドボム Acid Spray 40 100% 20 Single Black/White Black2/White2

Lv.54 Pan Coil とぐろをまく Coil - - 20 Self Black/White Black2/White2

Lv.59 Wild Volt ワイルドボルト Wild Charge 90 100% 15 Single Black/White Black2/White2

Lv.64 Gastro Acid - 100% 10 Single Black/White Black2/White2

Lv.69 Electromagnetic Cannon でんじほう Zap Cannon 120 50% 5 Single Black/White Black2/White2

Lv.74 Rampage あばれる Thrash 120 100% 10 Opponent Random Black/White Black2/White2

This is the list of skills you can learn after level 39 you can refer to, mainly Hundred Thousand Volt and Coil Scrolls, Wild Volt can be learned by the skill machine, and the other skills are not so good.

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